Hmmm, the use of 'humanoid' often changes, but going with 'Non Human'

In an order that changes regularly,

Spock (TOS)
Garak (DS9)
Kal-El (aka, Superman, aka Clark Kent. But as this is a non human question i'll use that name)
Salem (The cat from Sabrina the teenage witch)
Dory (Finding Nemo... What?)